Is Ozone Really the Culprit?

Smog is chemical mixture of gases that commonlywhere there is an extremely high level of
forms a brownish-yellow haze in the air, primarily overhydrocarbons in the air, nature simply cannot keep up
urban areas. Components of smog includewithout overcompensating.
ground-level ozone, nitrogen oxides (NOx), volatileBy itself, ozone is a natural purification agent used in
organic compounds (VOC), sulfur dioxide, acidica variety of ways for this purpose both by nature
aerosols and gases, and particulate matter. Theseand by humans. At reasonable levels it is not at all
gases result from a reaction between certain airborneunhealthy, and due to ozone's reactive and unstable
pollutants and strong sunlight. Smog poses anature it is very, very rare for ozone levels to
significant threat to animal, plant, and human life. Inbecome excessive under natural or normal
fact thousands die every year as a result of thiscircumstances. Conversely, man-made hydrocarbons
pollution. are completely unhealthy at any level and under any
The ground level ozone that is said to be the "maincircumstance. Common sense dictates that black,
culprit" in smog is really a collection of hydrocarbons,sooty smoke coming from an automobile exhaust or
CO2, CO, and SO2 that react with UV rays from thesmokestack can only be harmful to our health.
sun to form nitric oxides (NOX), halogenatedHydrocarbons do occur naturally in the air, as does
by-products, and sulfur compounds. Thesethe ozone that helps to break them down without
composites do indeed cause offensive odors,reaching dangerous or unnatural concentrations. When
aggravate respiratory problems and burn eyes. But itexcessive amounts of hydrocarbons are produced,
is not the ozone that is the true villain. Ozonelargely man-made, we will get high ozone
naturally forms not as a true component of smogconcentrations as a natural reaction to an unnatural
but, more accurately, as a means of eliminating it. Assituation. Rarely do less-populated areas experience
the level of VOCs and particulate rises in the air, thesmog and ozone problems, even though ozone is
ozone level rises as nature herself tries to clean upnaturally produced the same way and in similar
man's mess.quantities in big and small cities alike. 
If we remove the manmade components of smog,Modern, "air-tight" construction methods that began in
the VOCs and industrial particulates then we simplythe energy-conscious 1970s, combined with
have a natural process where the ozone and nitrogenmisinformation about ozone safety perpetuated by
dioxide are normalized to safe and healthy levels.well-meaning public health agencies, has resulted in an
When we add a large amount of man-madeunfortunate lack of ozone in most indoor
hydrocarbons to the atmosphere, then the amountsenvironments. The reason this is so unfortunate is
of nitrogen dioxide and ozone are artificially increased.because in truth ozone is an effective, natural air
The main reason that ozone gets the label of "Publicpurification agent which, when properly produced by
Enemy Number One" is that while man-madea high-quality air cleaning system, can alleviate a wide
hydrocarbons are very complex and as such quiterange of health problems such as allergies, asthma,
difficult to measure, ozone is very easy to accuratelysinus problems, and chemical exposure. It has been
measure. Consequently, ozone has long been used asstated by many environmental agencies in no
an indicator for the severity or presence of smoguncertain terms that indoor air pollution is the number
because as the levels of the true components ofone environmental health problem - and it is a far
smog rise, so does the level of ozone. Bymore significant risk to human health than even the
conveniently placing the onus on ozone, governmentworst outdoor air pollution. Because it is the high
and industry are effectively relieved of thehydrocarbon concentration that is a component of
responsibility for the millions of pounds of toxinssmog conditions that makes the ground ozone level
released into the air every year. Rather than takingartificially high, this is not a factor indoors. Even if we
steps to control the real culprit, we are actuallyhave many other kinds of pollutants in our home (and
allowing our government to shoot the messenger -we do), hydrocarbons are the only contaminant that
good guy ozone.cause ozone levels to rise above safe levels. The
Ozone's beneficial role in smog reduction is its abilityscientific community is still not sure exactly why this
to break down and oxidize hydrocarbons andhappens; what they only know is that it does
particulates in the air. One of the most powerfulhappen.
oxidants known, ozone actually burns and destroysIt should be clear that ozone is not the culprit of our
particulate with which it comes in contact. Ozone ispollution problems at ground level. Ozone has been
unstable and highly reactive, and as such it readilyused for half a century as a purifying agent for a
seeks out molecules of particulate and gas withvariety of applications - water treatment and
which to chemically react in an effort to break up thepurification, food preservation, cancer and HIV
oxygen triplet - O3 - and return to its natural state:treatment, and odor removal. Most ozone air purifiers
O2, or dioxygen. However, in the process of breakingare designed to produce an ozone concentration of
down man-made hydrocarbons in particular, the resultabout .04 ppm (parts per million) when operated
is the production of elements that combine toaccording to instructions, which is within all standards.
produce additional ozone and nitrogen dioxide, aboveFortunately, ozone is a self-policing element, since its
and beyond what is produced naturally. Even thoughodor becomes obnoxious to most well before it
hydrocarbons are quickly being broken down by thebecomes a health hazard, as opposed to the
ozone, the sheer volume of these pollutants that isrefreshing and purified smell it gives off when
produced by our highly-industrialized society is almostoccurring at safe and healthy levels.
insurmountable. In our cities and industrial areas,